Ligand field theory, Pauli shields and ultra-covalency in organometallic chemistry
Robert J. Deeth
Abstract
ligand field regime. However, within the ligand field regime, the bonding in 'coordination complexes' and 'organometallic compounds' has the same conceptual footing and the nature of the local σ, π and δ interactions can be extracted from analysing the ligand field d orbitals.
Topics & Concepts
Ligand field theoryShieldsPauli exclusion principleOrganometallic chemistryField (mathematics)ChemistryComputational chemistryLigand (biochemistry)Group 2 organometallic chemistryCoordination complexTheoretical physicsCrystallographyPure mathematicsPhysicsMathematicsCondensed matter physicsOrganic chemistryQuantum mechanicsMoleculeMetalCrystal structureIonElectromagnetic shieldingBiochemistryReceptorOrganometallic Complex Synthesis and CatalysisMagnetism in coordination complexesInorganic and Organometallic Chemistry