Divergent CO<sub>2</sub> Activation by Tuning the Lewis Acid in Iron‐Based Bimetallic Systems
Helena Corona, Marina Pérez‐Jiménez, Felipe de la Cruz‐Martínez, Israel Fernández, Jesús Campos
Abstract
Abstract Bimetallic motifs mediate the selective activation and functionalization of CO 2 in metalloenzymes and some recent synthetic systems. In this work, we build on the nascent concept of bimetallic frustrated Lewis pairs (FLPs) to investigate the activation and reduction of CO 2 . Using the Fe 0 fragment [(depe) 2 Fe] (depe=1,2‐bis(diethylphosphino)ethane) as base, we modify the nature of the partner Lewis acid to accomplish a divergent and highly chemoselective reactivity towards CO 2 . [Au(PMe 2 Ar)] + irreversibly dissociates CO 2 , Zn(C 6 F 5 ) 2 and B(C 6 F 5 ) 3 yield different CO 2 adducts stabilized by push‐pull interactions, while Al(C 6 F 5 ) 3 leads to a rare heterobimetallic C−O bond cleavage, and thus to contrasting reduced products after exposure to dihydrogen. Computational investigations provide a rationale for the divergent reactivity, while Energy Decomposition Analysis‐Natural Orbital for Chemical Valence (EDA‐NOCV) method substantiates the heterobimetallic bonding situation.