WO<sub>3</sub> Nanosheet/ZnIn<sub>2</sub>S<sub>4</sub> S-Scheme Heterojunctions for Enhanced CO<sub>2</sub> Photoreduction
Ao Xu, Yukai Zhang, Hougang Fan, Xiaoyan Liu, Fengyou Wang, Xin Qu, Lili Yang, Xin Li, Jian Cao, Maobin Wei
Abstract
The nanostructure of the photocatalyst plays a crucial role in determining its catalytic ability. In this paper, a 2D/2D WO 3 /ZnIn 2 S 4 S-scheme heterojunction was successfully prepared through a simple hydrogen reaction. Under UV–vis light irradiation, the yield of CO in the CO 2 photoreduction process using WO 3 /ZnIn 2 S 4 as the catalyst reached about 44.61 μmol·g –1, which was about 3.9 times higher than that obtained with ZnIn 2 S 4 alone. Cycling experiments demonstrated that the binary composite exhibited excellent photocatalytic activity and material stability. Photoelectrochemical measurements revealed that the 2D/2D WO 3 /ZnIn 2 S 4 S-scheme heterojunction significantly enhanced the separation efficiency of photogenerated carriers and effectively improved the redox ability of the photocatalyst. Density functional theory calculations were employed to analyze the electron transfer pathways and the formation of the built-in electric field at the 2D/2D WO 3 /ZnIn 2 S 4 interface, confirming that the heterojunction structure accelerated the transfer of photogenerated electrons from WO 3 to ZnIn 2 S 4 . The CO 2 photoreduction process was further investigated by in situ FTIR. Finally, a possible S-scheme electron transfer mechanism at the 2D–2D WO 3 /ZnIn 2 S 4 interface during the CO 2 photoreduction reaction was proposed and discussed.