Quantification of the mixed-valence and intervalence charge transfer properties of a cofacial metal–organic framework <i>via</i> single crystal electronic absorption spectroscopy
Patrick W. Doheny, Jack K. Clegg, Floriana Tuna, David Collison, Cameron J. Kepert, Deanna M. D’Alessandro
Abstract
parameter. This work demonstrates the first report of the successful characterisation of IVCT in a MOF material using single crystal electronic absorption spectroscopy and serves as an attractive alternative to more complex methods due to its simplicity and applicability.
Topics & Concepts
Valence (chemistry)Chemical physicsMetal-organic frameworkCharge (physics)MetalAbsorption spectroscopyMaterials scienceSpectroscopySingle crystalPhotochemistryNanotechnologyChemistryOptoelectronicsCrystallographyPhysical chemistryAdsorptionOrganic chemistryOpticsPhysicsQuantum mechanicsMetallurgyMetal-Organic Frameworks: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchElectrochemical Analysis and Applications