Role of Spin–Orbit Coupling in Long Range Energy Transfer in Metal–Organic Frameworks
Arnab Chakraborty, Stefan Ilić, Meng Cai, Bradley Gibbons, Xiaozhou Yang, Connor C. Slamowitz, Amanda J. Morris
Abstract
= 88 ± 10 Å) represents one of the largest Förster distances observed in an MOF. Collectively, this work contributes to the general knowledge of energy transfer in materials and provides groundwork for efficient utilization in artificial photosynthetic assemblies.
Topics & Concepts
ChemistryChromophoreDipoleChemical physicsSinglet stateArtificial photosynthesisMetal-organic frameworkEnergy transferWork (physics)Coupling (piping)Energy transformationSpin–orbit interactionNanotechnologyPhotochemistryAtomic physicsPhysical chemistryExcited stateThermodynamicsCondensed matter physicsPhysicsMaterials sciencePhotocatalysisOrganic chemistryAdsorptionMetallurgyCatalysisMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes