The Effect of Sulfonate Groups in the Structure of Porous Aromatic Frameworks on the Activity of Platinum Catalysts Towards Hydrodeoxygenation of Biofuel Components
M. A. Kalinina, Л. А. Куликов, Kirill A. Cherednichenko, A. L. Maximov, Э. А. Караханов
Abstract
Platinum catalysts based on porous aromatic frameworks (PAF-30 and PAF-30–SO3H) have been synthesized. Properties of the obtained catalysts have been assessed via hydrogenation of guaiacol, veratrole, and pyrocatechol at 250°С and hydrogen pressure 3.0 MPa in isopropanol medium. It has been shown that the presence of acidic sites in the catalyst significantly increases the yield of deoxygenation products. The effect of the substrate structure on the rate of its hydrodeoxygenation and the mechanism of the occurring processes have been studied.
Topics & Concepts
HydrodeoxygenationDeoxygenationCatalysisChemistryGuaiacolPlatinumYield (engineering)Organic chemistryChemical engineeringSelectivityMaterials scienceMetallurgyEngineeringCatalysis and Hydrodesulfurization StudiesCatalysis for Biomass ConversionCatalytic Processes in Materials Science