Synthesis of UiO-66-Sal-Cu(OH)<sub>2</sub> by a Simple and Novel Method: MOF-Based Metal Thin Film as a Heterogeneous Catalyst for Olefin Oxidation
Fatemeh Moghadaskhou, Azadeh Tadjarodi, Afsaneh Mollahosseini, Ali Maleki
Abstract
Metal–organic frameworks (MOFs), particularly UiO-66-NH 2, are employed as a catalyst in many industrial catalyst applications. As converting catalysts into thin film significantly increases their catalytic properties for the epoxidation of olefins, we report a general approach to synthesizing MOF thin films (UiO-66-Sal-Cu(OH) 2 ). Using the postsynthesis method (PSM), UiO-66-NH 2 was functionalized with salicylaldehyde and entrapped on copper hydroxide nanoparticle surfaces using a modern strategy (MOF thin film). We used field-emission scanning electron microscopy (FE-SEM), EDX (energy-dispersive X-ray analysis), XRD (X-ray diffraction), FT-IR (Fourier transform infrared), BET (Brunauer–Emmett–Teller), TGA (thermogravimetric analysis), XPS (X-ray photoelectron spectroscopy), and ICP-MS (inductively coupled plasma mass spectrometry) to determine the structure and morphology of the synthesized UiO-66-Sal-Cu(OH) 2 . The oxidation of cyclooctene by the UiO-66-Sal-Cu(OH) 2 thin film was studied. Due to its advantages, such as being environmentally friendly (base metal-loaded catalyst, room temperature, solvent-free reaction), reusability, and high yield, this compound can be an appropriate catalyst for the oxidation of olefins.