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Activated Carbon Derived from Cucumber Peel for Use as a Supercapacitor Electrode Material

Meruyert Nazhipkyzy, Gulim Kurmanbayeva, Aigerim R. Seitkazinova, Esin Apaydın Varol, Wanlu Li, Balaussa K. Dinistanova, Almagul Issanbekova, Togzhan Mashan

2024Nanomaterials20 citationsDOIOpen Access PDF

Abstract

Biowaste conversion into activated carbon is a sustainable and inexpensive approach that relieves the pressure on its disposal. Here, we prepared micro-mesoporous activated carbons (ACs) from cucumber peels through carbonization at 600 °C followed by thermal activation at different temperatures. The ACs were tested as supercapacitors for the first time. The carbon activated at 800 °C (ACP-800) showed a high specific capacitance value of 300 F/g at a scan rate of 5 mV/s in the cyclic voltammetry and 331 F/g at the current density of 0.1 A/g in the galvanostatic charge–discharge analysis. At the current density of 1 A/g, the specific discharge capacitance was 286 F/g and retained 100% capacity after 2000 cycles. Their properties were analyzed by scanning electron microscopy, energy-dispersive X-ray analysis, porosity, thermal analysis, and Fourier-transform infrared spectroscopy. The specific surface area of this sample was calculated to be 2333 m2 g−1 using the Brunauer–Emmett–Teller method. The excellent performance of ACP-800 is mainly attributed to its hierarchical porosity, as the mesopores provide connectivity between the micropores and improve the capacitive performance. These electrochemical properties enable this carbon material prepared from cucumber peels to be a potential source for supercapacitor materials.

Topics & Concepts

SupercapacitorCarbonizationMaterials scienceCyclic voltammetryActivated carbonMesoporous materialCapacitanceCarbon fibersFourier transform infrared spectroscopySpecific surface areaChemical engineeringPorosityScanning electron microscopeCurrent densityElectrodeElectrochemistryComposite materialChemistryAdsorptionOrganic chemistryCatalysisComposite numberPhysical chemistryPhysicsEngineeringQuantum mechanicsSupercapacitor Materials and FabricationElectrospun Nanofibers in Biomedical ApplicationsConducting polymers and applications
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