Pentagonal-bipyramidal 4d and 5d complexes with unquenched orbital angular momentum as a unique platform for advanced single-molecule magnets: current state and perspectives
Vladimir S. Mironov, Tamara A. Bazhenova, Yu. V. Manakin, Eduard B. Yagubskii
Abstract
in PBP complexes with monoatomic apical μ-bridging ligands is examined. The basic principles of molecular engineering the highest barrier through anisotropic exchange interactions of PBP 4d/5d complexes are formulated. The theoretical and experimental results taken together indicate that the concept of high-performance SMMs based on 4d/5d PBP complexes with unquenched orbital angular momentum is an attractive alternative to the currently dominant lanthanide-based SMM strategy.
Topics & Concepts
CrystallographyPentagonal bipyramidal molecular geometryCluster (spacecraft)AnisotropyMagnetChemistryCondensed matter physicsMaterials scienceMolecular physicsPhysicsQuantum mechanicsCrystal structureComputer scienceProgramming languageMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies