Nickel-mediated N–N bond formation and N<sub>2</sub>O liberation <i>via</i> nitrogen oxyanion reduction
Daniel M. Beagan, Alyssa C. Cabelof, Maren Pink, Veronica Carta, Xinfeng Gao, Kenneth G. Caulton
Abstract
Deoxygenation of nitrogen oxyanions coordinated to nickel using reduced borylated heterocycles leads to N–N bond formation and N<sub>2</sub>O liberation. The nickel dimer product facilitates NO disproportionation, leading to a synthetic cycle.
Topics & Concepts
DeoxygenationDisproportionationNickelOxyanionChemistryNitrogenDimerLiberationMedicinal chemistryOrganic chemistryCatalysisBiochemistryIn vitroAmmonia Synthesis and Nitrogen ReductionAdvanced Photocatalysis TechniquesCO2 Reduction Techniques and Catalysts