A Bifunctional Photo‐Assisted Li–O<sub>2</sub> Battery Based on a Hierarchical Heterostructured Cathode
Malin Li, Xiaoxue Wang, Fei Li, Lijun Zheng, Ji‐Jing Xu, Jihong Yu
Abstract
Abstract Photo‐assisted charging is considered an effective approach to reducing the overpotential in lithium–oxygen (Li–O 2 ) batteries. However, the utilization of photoenergy during the discharge process in a Li–O 2 system has been rarely reported, and the functional mechanism of such a process remains unclear. Herein, a novel bifunctional photo‐assisted Li–O 2 system is established by employing a hierarchical TiO 2 –Fe 2 O 3 heterojunction, in which the photo‐generated electrons and holes play key roles in reducing the overpotential in the discharging and charging processes, respectively. Moreover, the morphology of the discharge product (Li 2 O 2 ) can be modified via the dense surface electrons of the cathode under illumination, resulting in promoted decomposition kinetics of Li 2 O 2 during the charging progress. Accordingly, the output and input energies of the battery can be tuned by illumination, giving an ultralow overpotential of 0.19 V between the charge and discharge plateaus with excellent cyclic stability (retaining a round‐trip efficiency of ≈86% after 100 cycles). The investigation of the bifunctional photo‐assisted process presented here provides significant insight into the mechanism of the photo‐assisted Li–O 2 battery and addresses the overpotential bottleneck in this system.