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Sterically enriched bulky 1,3-bis(<i>N</i>,<i>N</i>′-aralkyl)benzimidazolium based Pd-PEPPSI complexes for Buchwald–Hartwig amination reactions

Motakatla Venkata Krishna Reddy, Gokanapalli Anusha, Peddiahgari Vasu Govardhana Reddy

2020New Journal of Chemistry28 citationsDOI

Abstract

A simple and efficient synthesis of a series of unexisting Pd-PEPPSI complexes is summarized. These complexes are exploited for their high catalytic activity towards Buchwald–Hartwig amination.

Topics & Concepts

ChemistryAminationSteric effectsPalladiumMedicinal chemistryCatalysisCombinatorial chemistryOrganic chemistryN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling ReactionsCoordination Chemistry and Organometallics
Sterically enriched bulky 1,3-bis(<i>N</i>,<i>N</i>′-aralkyl)benzimidazolium based Pd-PEPPSI complexes for Buchwald–Hartwig amination reactions | Litcius