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Synthesis and Properties of Octadecyl Trimethyl Ammonium Polyacrylic Surfactants

Yan Jiao, Qiaona Liu, Weichao Du, Chengtun Qu, Zhifei Song, Jinling Li, Jie Zhang, Gang Chen

2020Tenside Surfactants Detergents22 citationsDOI

Abstract

Abstract In order to expand the application range of surfactants, octadecyl trimethyl ammonium chloride (OTAC) and polyacrylic acid (PAA) were used as raw materials to synthesize octadecyl trimethyl ammonium polyacrylic (OTAP). The molar ratios of OTAC to polyacrylic acid monomer were 1:1, 1:2 and 1:3. The synthesized compounds were named as OTAP-1, OTAP-2, OTAP-3. The obtained research results show that the best foaming ability was achieved with OTAP-1, and the best foam stability with OTAP-2. When the concentration was 2.0 g/L, the order of the emulsifying ability was: OTAP-1 > OTAP-2 > OTAP-3; when the concentration was 4.0 g/L, the emulsifying ability order was OTAP-2 > OTAP-3 > OTAP-1. OTAP-1 had a corrosion inhibition capacity of up to 85.11 %, and OTAP-2 and OTAP-3 had a sustained release rate of 81.06 % and 72.82 %, respectively. OTAP-3 had a good effect on scale inhibition, and the scale inhibition rate was 65.01 %.

Topics & Concepts

Polyacrylic acidChemistryAmmonium chlorideAmmoniumNuclear chemistryMonomerMolar ratioRaw materialOrganic chemistryCatalysisPolymerSurfactants and Colloidal SystemsPetroleum Processing and AnalysisEnhanced Oil Recovery Techniques
Synthesis and Properties of Octadecyl Trimethyl Ammonium Polyacrylic Surfactants | Litcius