Chemically bonded MXene/SnSe2 composite with special structural transformation as a high-performance anode for lithium and potassium ions battery
Yayi Cheng, Jianfeng Huang, Fangli Yu, Yingying Zhou, Guohao Li, Weijie Cheng, Pengfei Duan, Hui Qi, Hui Xie
Abstract
Sn-C bonding coupled MXene/SnSe 2 composite with SnSe 2 nanosheets vertically coating on the MXene surface was prepared successfully by the solvothermal method, in which MXene matrix etched separately by HF and LiF/HCl was used to explore the improving effect on the electrochemical performance of SnSe 2 . It is found that MXene etched by HF acid shows more obvious accordion-like structure with larger layer spacing, and its composite with SnSe 2 demonstrates better lithium and potassium storage properties. When employed as potassium-ion batteries (PIBs) anode, MXene/SnSe 2 electrode can deliver a reversible capacity of 222.8 mAh·g −1 till 300 cycles at the current density of 200 mA·g −1 . As an anode for lithium-ion batteries (LIBs), MXene/SnSe 2 could provide high reversible capacity (515.6 mAh·g −1 after 300 cycles at 200 mA·g −1 ) and rate capacity (1015.1 mAh·g −1 at 500 mA·g −1 and 496.2 mAh·g −1 at 5000 mA·g −1 ). Even at 2000 mA·g −1 , the capacity of MXene/SnSe 2 can be maintained at 322.6 mAh·g −1 after 500 cycles. Further analysis by ex-situ SEM finds that the MXene/SnSe 2 electrode undergoes structural reconstruction at the high current density of 2000 mA·g −1 . In the first few cycles, SnSe 2 nanosheets are changed into a network structure and then in-situ pulverized into many small nanoparticles , all which immerged on MXene surface and between layers. Although MXene/SnSe 2 electrode experiences structural transformation, it retains apparent layered structure. This provides a fast channel for electrons and ions migration, resulting in higher Li + diffusion rate and diffusion-controlled storage capacity. It is believed that the work could be acted as a reference for design composite with MXene and used for anode as well as other materials.