Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF3+, CF3•, and CF3– Reactivity

Hao Jia, Andreas P. Häring, Florian Berger, Li Zhang, Tobias Ritter

2021Journal of the American Chemical Society229 citationsDOI Open Access PDF

Abstract

in electrophilic, radical, and nucleophilic trifluoromethylation reactions.

Topics & Concepts

ChemistryTrifluoromethanesulfonateTrifluoromethylationTrifluoromethylReagentNucleophileElectrophileTriflic acidReactivity (psychology)Medicinal chemistryOrganic chemistryCatalysisAlternative medicineAlkylPathologyMedicineFluorine in Organic Chemistry

Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF<sub>3</sub><sup>+</sup>, CF<sub>3</sub><sup>•</sup>, and CF<sub>3</sub><sup>–</sup> Reactivity

Abstract

Topics & Concepts