A Method for Deconvoluting and Quantifying the Real‐Time Species Fluxes and Ionic Currents Using In Situ Electrochemical Quartz Crystal Microbalance
Kai Zheng, Yongqiu Xian, Zifeng Lin
Abstract
Abstract Electrochemical quartz crystal microbalance (EQCM) is a powerful tool to screen the gravimetric response of electrochemically active electrodes. In this study, a method is proposed to deconvolute and quantify the real‐time fluxes and ionic currents of different species based on the EQCM measurement results. This work creatively conceptualizes the flux cyclic voltammograms (CVs) and ionic current CVs, and applys them to analyze the real‐time molecules and ion evolution. As a proof of concept, Ti 3 C 2 T x MXene, the most studied 2D metal carbide, is investigated as a supercapacitor electrode in 1 m H 2 SO 4 electrolyte. The real‐time H 2 O and H + fluxes are obtained using the proposed approach and corresponding flux CVs are constructed. The potential‐dependent evolution of H 2 O and H + fluxes suggest that the insertion of hydrated H + contributes significantly to the double‐layer capacitance. The H + CV calculated from the H + flux overlaps with the experimental measured CV, confirming that H + is the only interactive charge carrier for screening the Ti 3 C 2 T x electrode charge.