Tellurium Treatment for the Modification of Sulfide Inclusions and Corresponding Industrial Applications in Special Steels: A Review
Xiangyu Xu, Qianren Tian, Tao Hu, Dengping Ji, Quan Qian, Jianxun Fu
Abstract
Tellurium treatment is used to control the morphology of manganese sulfide (MnS) inclusions, reduce the mechanical anisotropy, and improve the machinability of sulfur‐bearing steels, such as free‐cutting steels, super free‐cutting steels, medium‐carbon microalloyed steels, and die steels. The boiling point of tellurium is low, and it is mainly added to steel in the form of fine particles wrapped in a cored wire. In steels, tellurium mainly exists in the form of Mn(S, Te) inclusions or MnTe–MnS composite inclusions. The strength of MnS inclusions is increased through tellurium doping; thus, the aspect ratio of sulfide after hot working is significantly decreased through tellurium treatment. However, the tellurium content in steel should not be too high; otherwise, brittle compounds will form and cause embrittlement, particularly in high‐alloyed steels. The Te/S mass ratio is considered an important factor in tellurium treatment. When the Te/S mass ratio in steel is 0.2, the aspect ratio of the as‐cast sulfide could be controlled within the optimal range. During steelmaking, the yield of Te can be improved by reducing the basicity of the slag and decreasing the time of Te evaporation. Through data‐driven material design, Te treatment technology undergoes broader development.