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High-speed growth of thick high-purity β-Ga<sub>2</sub>O<sub>3</sub> layers by low-pressure hot-wall metalorganic vapor phase epitaxy

Junya Yoshinaga, Haruka Tozato, Takahito Okuyama, Shogo Sasaki, Guanxi Piao, Kazutada Ikenaga, Ken Goto, Y. Ban, Yoshinao Kumagai

2023Applied Physics Express24 citationsDOIOpen Access PDF

Abstract

Abstract High-speed growth of thick, high-purity β -Ga 2 O 3 homoepitaxial layers on (010) β -Ga 2 O 3 substrates by low-pressure hot-wall metalorganic vapor phase epitaxy was investigated using trimethylgallium (TMGa) as the Ga precursor. When the reactor pressure was 2.4–3.4 kPa, the growth temperature was 1000 °C, and a high input VI/III (O/Ga) ratio was used, the growth rate of β -Ga 2 O 3 could be increased linearly by increasing the TMGa supply rate. A thick layer was grown at a growth rate of 16.2 μ m h −1 without twinning. Incorporated impurities were not detected, irrespective of the growth rate, demonstrating the promising nature of β -Ga 2 O 3 growth using TMGa.

Topics & Concepts

TrimethylgalliumGrowth rateVapor phaseMaterials scienceEpitaxyImpurityChemical vapor depositionAnalytical Chemistry (journal)Metalorganic vapour phase epitaxyPhase (matter)Layer (electronics)ChemistryOptoelectronicsNanotechnologyThermodynamicsChromatographyGeometryMathematicsPhysicsOrganic chemistryGa2O3 and related materialsZnO doping and propertiesAdvanced Photocatalysis Techniques
High-speed growth of thick high-purity β-Ga<sub>2</sub>O<sub>3</sub> layers by low-pressure hot-wall metalorganic vapor phase epitaxy | Litcius