Crystalline heaviest pnictogen-dipyrromethenes: isolation, characterization, and reactivity
Chen Liu, Chen Liu, Yuyang Dai, Qiqi Han, Chunmeng Liu, Chunmeng Liu, Yuanting Su
Abstract
(Pn = Sb, 3; Bi 4), which are direct analogues of boron-dipyrromethene (BODIPY), have been readily prepared and isolated as crystalline solids. Both compounds display green photoluminescence with small full widths at half maximum in toluene. Moreover, the reduction of 3 with sodium metal afforded the cyclic dicoordinate stibinidene 5.
Topics & Concepts
PnictogenCharacterization (materials science)Reactivity (psychology)Isolation (microbiology)ChemistryMaterials scienceNanotechnologyPhysicsBiologyBioinformaticsCondensed matter physicsMedicineSuperconductivityPathologyAlternative medicineLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistryPerovskite Materials and Applications