Functional and protective hole hopping in metalloenzymes
Harry B. Gray, Jay R. Winkler
Abstract
. In many cases these chains may serve a protective role in metalloenzymes by deactivating high-potential reactive intermediates formed in uncoupled catalytic turnover.
Topics & Concepts
ChemistryDensity functional theoryCombinatorial chemistryNanotechnologyMaterials scienceComputational chemistryPorphyrin Metabolism and DisordersPhotosynthetic Processes and MechanismsEnzyme Structure and Function