From ZnF<sub>2</sub> to ZnF<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge
Yue‐Qi Wei, Wei Xu, Lei Huai, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang
Abstract
Exploring nonlinear optical (NLO) materials with short ultraviolet cutoff edges are significant for developing an all-solid-state laser. Here, a noncentrosymmetric zinc fluoride hydrate, ZnF 2 (H 2 O) 4, was synthesized by a hydrothermal method. It crystallizes in the polar space group of Pca 2 1 . The compound consists of the central Zn 2+ combined with F – and coordination water to form the [ZnF 2 (H 2 O) 4 ] octahedra, and each octahedron is isolated from each other to form a 0-dimensional structure. As an acentric compound, ZnF 2 (H 2 O) 4 shows a phase-matchable second-harmonic-generation (SHG) activity with an intensity about 0.5 times that of KH 2 PO 4 . More attractively, it also shows a short ultraviolet cutoff edge below 200 nm, which is rare in reported halide hydrate systems. Interestingly, from ZnF 2 to ZnF 2 (H 2 O) 4, the partial substitution of the coordinated F atoms by H 2 O molecules leads to the structural transformation from centric to acentric with SHG activity off to on. Structural analyses, NLO activity, and theoretical calculations are presented in this work.