NIR-absorbing and emitting α,α-nitrogen-bridged BODIPY dimers with strong excitonic coupling
Long Wang, Cheng Cheng, Changjiang Yu, Qinghua Wu, Zhengxin Kang, Hua Wang, Lijuan Jiao, Erhong Hao
Abstract
New NIR α,α-NH-bridged BODIPY dimers with strong excitonic coupling and enhanced electron spin delocalization via nitrogen bridges were synthesized for the first time.
Topics & Concepts
BODIPYDelocalized electronPhotochemistryChemistryNitrogenCoupling (piping)NucleophileElectron delocalizationNucleophilic substitutionFluorescenceCrystallographyMaterials scienceOrganic chemistryPhysicsCatalysisQuantum mechanicsMetallurgyLuminescence and Fluorescent MaterialsNanoplatforms for cancer theranosticsMolecular Sensors and Ion Detection