Synthesis of pyranopyrazole and pyranopyrimidine derivatives using magnesium oxide nanoparticles and evaluation as corrosion inhibitors for lubricants
Ahmad R. Salih, Zainab A. K. Al-Messri
Abstract
A three-component, one pot reaction was used to synthesize different pyranopyrazole, tetrahydrochromene, and pyranopyrimidine derivatives using magnesium oxide nanoparticles with a faster reaction time, higher yield, and higher purity than a conventional piperidine base catalyst. The prepared compounds were identified by FT-IR, 1HNMR, 13CNMR spectroscopy, and evaluated as good copper corrosion inhibitors by blending with a base stock lubricant provided by the Iraqi Midland Refineries Company/Al-Daura according to ASTM–D130.
Topics & Concepts
LubricantMagnesiumPiperidineCorrosionCatalysisCopperOxideYield (engineering)NanoparticleBase oilNuclear chemistryMaterials scienceChemistryMetallurgyInorganic chemistryOrganic chemistryNanotechnologyScanning electron microscopeComposite materialMulticomponent Synthesis of HeterocyclesInorganic and Organometallic ChemistrySynthesis and biological activity