[3 + 2] Cycloaddition of azides with arynes formed<i>via</i>C–H deprotonation of aryl sulfonium salts
Xing-Wei Gu, Yan-Hua Zhao, Xiao‐Feng Wu
Abstract
Herein, we developed a new methodology of using aryl sulfonium salts as the aryne precursor for [3 + 2] cycloaddition reactions with azides.
Topics & Concepts
AryneSulfoniumCycloadditionArylDeprotonationChemistryMedicinal chemistryOrganic chemistryCombinatorial chemistrySalt (chemistry)CatalysisIonAlkylCyclization and Aryne ChemistryChemical Reactions and MechanismsCatalytic Alkyne Reactions