Two Copper-Carbenes from One Diazo Compound
María Álvarez, María Besora, Francisco Molina, Feliu Maseras, Tomás R. Belderraín, Pedro J. Pérez
Abstract
) complex is also formed. Experimental data, DFT calculations, and microkinetic models allow us to propose that the latter undergoes CO loss en route to the former.
Topics & Concepts
CarbeneDiazoChemistryDecarbonylationIntramolecular forceLigand (biochemistry)CyclopropanationCarbon monoxideCopperMedicinal chemistryPhotochemistryStereochemistryOrganic chemistryCatalysisBiochemistryReceptorCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsCatalytic Alkyne Reactions