Toward MBenes Battery Electrode Materials: Layered Molybdenum Borides for Li‐Ion Batteries
Ahmad Majed, Mohammad Torkamanzadeh, Chukwudi F. Nwaokorie, Karamullah Eisawi, Chaochao Dun, Audrey Buck, Jeffrey J. Urban, M. M. Montemore, Volker Presser, Michael Naguib
Abstract
Abstract Lithium‐ion and sodium‐ion batteries (LIBs and SIBs) are crucial in our shift toward sustainable technologies. In this work, the potential of layered boride materials (MoAlB and Mo 2 AlB 2 ) as novel, high‐performance electrode materials for LIBs and SIBs, is explored. It is discovered that Mo 2 AlB 2 shows a higher specific capacity than MoAlB when used as an electrode material for LIBs, with a specific capacity of 593 mAh g −1 achieved after 500 cycles at 200 mA g −1 . It is also found that surface redox reactions are responsible for Li storage in Mo 2 AlB 2 , instead of intercalation or conversion. Moreover, the sodium hydroxide treatment of MoAlB leads to a porous morphology and higher specific capacities exceeding that of pristine MoAlB. When tested in SIBs, Mo 2 AlB 2 exhibits a specific capacity of 150 mAh g −1 at 20 mA g −1 . These findings suggest that layered borides have potential as electrode materials for both LIBs and SIBs, and highlight the importance of surface redox reactions in Li storage mechanisms.