Plasma-promoted reactions of the heterobimetallic anions CuNb<sup>−</sup> with dinitrogen and subsequent reactions with carbon dioxide: formation of C–N bonds
Lan-Ye Chu, Yongqi Ding, Ming Wang, Jia‐Bi Ma
Abstract
Plasma effect promotes the dissociation of NN bonds on the heterobimetallic anion CuNb − , leading to the formation of CuNbN 2 − . CuNbN 2 − further reacts with CO 2 to obtain NCO − , therefore N 2 and CO 2 coupling reaction is realized at room temperature.
Topics & Concepts
ChemistryDissociation (chemistry)MoleculeCoupling reactionSurface modificationPhotochemistryCarbon dioxideCatalysisOrganic chemistryPhysical chemistryCarbon dioxide utilization in catalysisAmmonia Synthesis and Nitrogen ReductionMXene and MAX Phase Materials