Solar Light Responsive Graphitic Carbon Nitride Coupled Porphyrin Photocatalyst that Uses for Solar Fine Chemical Production
Shaifali Mishra, Rajesh K. Yadav, Satyam Singh, Surabhi Chaubey, Pooja Singh, Chandani Singh, Sarvesh Kumar Gupta, Shivani Gupta, Dhanesh Tiwary, Tae Wu Kim
Abstract
Abstract Photocatalysis is a defendable manner for production of several organic chemicals, energy and its storage from solar energy. For the evolution of metal free, cost‐effective catalyst a 2D composite has been appear as a photocatalyst. Here, we had reported the synthesis of a light harvesting composite as a photocatalyst which was assembled by a poly‐condensation mechanism between graphitic carbon nitride and tetrakis(4‐nitrophenyl) porphyrin and the resulting composite manifest the excellent light harvesting properties, suitable energy band and low charge recombination. The photocatalyst [(NO 2 ) 4 TPP@g‐C 3 N 4 ] enables the efficient photocatalytic production of nicotinamide adenine dinucleotide (NADH) from consumed NAD + also the production of organic chemicals like 4‐methoxybenzylimines from 4‐methoxybenzylamines. The photocatalytic efficiency of the photocatalyst was estimated by the percentage of NADH regeneration and the percentage yield of organic transformations. It shows the tetrakis(4‐nitrophenyl) porphyrin could enhance the charge transfer capacity of graphitic carbon nitride which shows excellent photocatalysis activities and organic transformations.