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One-step hydrothermal synthesis of CuS/MoS2 composite for use as an electrochemical non-enzymatic glucose sensor

Krishna Prasad Sharma, Miyeon Shin, Ganesh Prasad Awasthi, S.J. Cho, Changho Yu

2023Heliyon31 citationsDOIOpen Access PDF

Abstract

Early diagnosis may be crucial for the prevention of chronic diabetes mellitus. For that herein, we prepared a CuS/MoS 2 composite for a non-enzymatic glucose sensor through a one-step hydrothermal method owing to the synergetic effect of CuS/MoS 2 . The surface morphology of CuS/MoS 2 was studied by Field Emission Scanning Electron Microscopy (FESEM) and Cs-corrected Scanning Transmission Electron Microscopy (Cs-STEM). The crystallinity and surface composition of CuS/MoS 2 were analyzed by X-ray Diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS) respectively. The working electrode was prepared from CuS/MoS 2 electrocatalyst, and for that dispersed solution of electrocatalyst was used to fabricate the material-loaded glassy carbon electrode (GC). CuS/MoS 2 composite shows the viability of electrocatalyst to oxidize glucose in an alkaline solution with sensitivity and detection limit of 252.71 μA mM −1 cm −2 and 1.52 μM respectively. The proposed glucose sensor showed reasonable stability and potential selectivity during electrochemical analysis. Accordingly, the CuS/MoS 2 composite has potential as a viable material for glucose sensing in diluted human serum.

Topics & Concepts

Hydrothermal circulationComposite numberElectrochemistryHydrothermal synthesisEnzymeChemical engineeringMaterials scienceNanotechnologyChemistryBiochemistryEngineeringComposite materialElectrodePhysical chemistryElectrochemical sensors and biosensorsElectrochemical Analysis and ApplicationsConducting polymers and applications