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Covalent Organic Frameworks for the Oxygen Reduction Reaction: Designing Strategies

Shuai Yang, Xuewen Li, Shiyuan Fei, Qing Xu, Zheng Jiang

2024ChemCatChem11 citationsDOIOpen Access PDF

Abstract

Abstract Covalent organic frameworks (COFs) are an emerging crystalline polymer that is constructed by the organic blocks through reversible polymerization. In this review, we have summarized the strategies for designing covalent organic frameworks for the oxygen reduction reaction. The discussion involved the new structural design of COFs and modifications fitting to the applications. Active sites manipulated scale from the single atom‘s electron states to the body framework arrangements. This review has anticipated the researchers to enlighten new ORR catalyst designing and optimization.

Topics & Concepts

Covalent bondDynamic covalent chemistryCatalysisPolymerizationPolymerChemistryOrganic synthesisOxygen reduction reactionCovalent organic frameworkMolecular oxygenNanotechnologyOrganic polymerOxygen atomReduction (mathematics)Combinatorial chemistryMaterials scienceOrganic chemistryMoleculeSupramolecular chemistryElectrochemistryGeometryPhysical chemistryElectrodeMathematicsCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesFuel Cells and Related Materials