Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates
Yu‐Jie Zhong, Jian‐Hong Liao, Tzu‐Hao Chiu, Ying‐Yann Wu, Samia Kahlal, Jean‐Yves Saillard, C. W. Liu
Abstract
(x = 1-6). An interstitial hydride lying at the center of a tricapped tetrahedral cage was located and refined anisotropically by using X-ray data, and its presence acertained by multinuclear NMR spectroscopy and DFT calculations.
Topics & Concepts
Bimetallic stripHydrideCrystallographyChemistryMetalOrganic chemistryNanocluster Synthesis and ApplicationsMetalloenzymes and iron-sulfur proteinsHydrogen Storage and Materials