Mechanochemical aerobic oxidative Heck coupling by polymer-assisted grinding: cyclodextrin additive facilitating regioselectivity control
Keyu Xiang, Haowen Shou, Chenhui Hu, Weike Su, Jingbo Yu
Abstract
A novel approach utilizing the polymer-assisted grinding (POLAG) technique to facilitate the regioselective oxidative Heck coupling of aryl boronic acids with electronically unbiased olefins under solvent-free conditions was presented.
Topics & Concepts
RegioselectivityCyclodextrinChemistryOxidative phosphorylationMechanochemistryGrindingHeck reactionPolymerOxidative coupling of methanePolymer chemistryOrganic chemistryCatalysisPalladiumMaterials scienceMetallurgyBiochemistryPlant-based Medicinal ResearchBotulinum Toxin and Related Neurological DisordersPhosphorus compounds and reactions