Stereoselective Synthesis of (±)-Cephanolide B
Anding Li, Ziru He, Bingyan Liu, Zhen Yang, Zichun Zhang
Abstract
, to construct the ABC-tricyclic rings (6-5-6); and (iii) a phthaloyl peroxide-mediated arene oxygenation to install the C-13 phenol group.
Topics & Concepts
ChemistryStereoselectivityAromatizationIntramolecular forceRing (chemistry)Intermolecular forceTandemTotal synthesisStereochemistryPhenolMedicinal chemistryMoleculeOrganic chemistryCatalysisMaterials scienceComposite materialBiological Activity of Diterpenoids and BiflavonoidsAdvanced Synthetic Organic ChemistrySynthetic Organic Chemistry Methods