Defluorophosphorylation of fluoroalkyl peroxides for the synthesis of highly substituted furans
Xue‐Qiang Chu, Song‐Zhou Cai, Jiawei Chen, Zi-Lun Yu, Mengtao Ma, Patrick J. Walsh, Zhi‐Liang Shen
Abstract
A highly tunable defluorophosphorylation of fluorinated peroxides for the preparation of C 3,4-diphosphoryl furans and C 4-monophosphoryl furans under conditions with no added transition metals is disclosed.
Topics & Concepts
ChemistryOrganic chemistryCombinatorial chemistryFluorine in Organic ChemistryOrganophosphorus compounds synthesisCatalytic Cross-Coupling Reactions