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C(sp<sup>3</sup>)–H bond functionalization with styrenes <i>via</i> hydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis

Shogo Mori, Susumu Saito

2021Green Chemistry21 citationsDOI

Abstract

The redox-neutral addition of α-C–H bonds to styrenes was enabled <italic>via</italic> the hydrogen-atom transfer to aqueous hydroxyl radical generated by the oxidation of water under silver-nanoparticle-loaded titania photocatalysis.

Topics & Concepts

ChemistryPhotocatalysisSurface modificationAqueous solutionHydrogen atomPhotochemistryHydroxyl radicalHydrogen bondAtom (system on chip)HydrogenRadicalOrganic chemistryCatalysisGroup (periodic table)Physical chemistryMoleculeComputer scienceEmbedded systemAdvanced Photocatalysis TechniquesCatalytic C–H Functionalization MethodsRadical Photochemical Reactions
C(sp<sup>3</sup>)–H bond functionalization with styrenes <i>via</i> hydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis | Litcius