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Current Induced Spin-Polarization in Chiral Molecules

Jonas Fransson, Luca Turin

2024The Journal of Physical Chemistry Letters13 citationsDOIOpen Access PDF

Abstract

The inverse spin-galvanic effect or current-induced spin-polarization is mainly associated with interfaces between different layers in semiconducting heterostructures, surfaces of metals, and bulk semiconducting materials. Here, we theoretically predict that the inverse spin-galvanic effect should also be present in chiral molecules, as a result of the chiral induced spin selectivity effect. As proof-of-principle, we calculate the nonequilibrium properties of a model system that previously has been successfully used to explain a multitude of aspects related to the chiral induced spin selectivity effect. Here we show that current driven spin-polarization in a chiral molecule gives rise to a magnetic moment that is sensitive to external magnet field. The chiral molecule then behaves like a soft ferromagnet. This, in turn, suggests that magnetic permeability measurement in otherwise nonmagnetic systems may be used noninvasively to detect the presence of spin-polarized currents.

Topics & Concepts

Condensed matter physicsNon-equilibrium thermodynamicsSpin polarizationSpin (aerodynamics)MoleculePolarization (electrochemistry)Materials scienceMagnetic fieldInverseFerromagnetismSpin Hall effectMagnetic momentPhysicsChemistryQuantum mechanicsPhysical chemistryMathematicsElectronGeometryThermodynamicsQuantum and electron transport phenomenaMagnetic properties of thin filmsMolecular Junctions and Nanostructures
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