Biomimetic Heteromodulus All-Fluoropolymer Piezoelectric Nanofiber Mats for Highly Sensitive Acoustic Detection
Yujie Wu, Chunyan Tang, Shan Wang, Jiaxing Guo, Jing Qi, Junhong Liu, Kai Ke, Yu Wang, Wei Yang
Abstract
Flexible piezoelectric pressure sensors have aroused a plethora of applications in wearable electronics, acoustic transducers, and energy harvesters thanks to many merits such as prompt response, good signal linearity, and ease of shaping. However, as all-polymer piezoelectric films have a low piezoelectric coefficient and severe stress dissipation, it is currently challenging to achieve a high piezoelectric output for the foregoing applications without introducing nanomaterials or piezoelectric ceramics. Here, we report a local stress engineering strategy to fabricate biomimetic all-fluoropolymer piezoelectric film pressure sensors with high-modulus poly(vinylidene fluoride) (PVDF) nanospheres embedded on low-modulus poly(vinylidene fluoride-trifluoride ethylene) (PVDF-TrFE) nanofibers for highly sensitive acoustic detection. High-modulus PVDF nanospheres create many local stress concentration sites on PVDF-TrFE nanofibers and increase the local deformation, leading to significantly improved force/pressure sensitivity. As such, by comparison with the force sensitivity of 60 mV/N for neat PVDF-TrFE, the heteromodulus fiber mats with 10 wt % PVDF nanospheres can achieve a force sensitivity of 145.1 mV/N over 0-25 N dynamic impact force (i.e., 0 ∼ 250 kPa pressure), together with an acoustic detection limit as low as 60 dB or 0.02 Pa.