High‐Performance Air‐Stable 2D‐WSe<sub>2</sub>/P3HT Based Inorganic–Organic Hybrid Photodetector with Broadband Visible to Near‐IR Light Detection
Prabal Dweep Khanikar, Sheetal Dewan, J. John, Atul Shukla, P.K. Das, Sajal Dhara, Supravat Karak, Shih‐Chun Lo, Ebinazar B. Namdas, Samaresh Das
Abstract
Abstract Photodetectors that can achieve high‐speed photoresponse and high responsivity with broadband detection are essential for bio‐health monitoring, imaging, chemical sensing, and many other applications. Herein a high‐performance inorganic–organic hybrid photodetector based on a heterojunction of exfoliated 2D tungsten diselenide (WSe 2 ) layers and solution‐processable poly(3‐hexylthiophene‐2,5‐diyl), P3HT is reported. The heterojunction shows enhanced exciton harvesting through long‐range energy transfer from P3HT to WSe 2 , which is confirmed using photoluminescence quenching and fluorescence decay measurements. The detector shows broadband light detection from visible to near‐infrared (NIR) (400−1100 nm), and air‐stable device performance. The device exhibits the highest responsivity of 17.6 AW −1 for low incident light intensity (<10 −5 W cm −2 ) at 640 nm wavelength of light. Furthermore, a fast photoresponse speed with a rise/fall time of 9.5/5.1 µs, which retained its performance for more than four months under ambient conditions is demonstrated. The superior device performance presented here using an inorganic–organic hybrid heterojunction is the key to producing novel high‐performance and air‐stable photodetectors with broad spectral bandwidth.