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Synthesis of π-Extended Thiele’s and Chichibabin’s Hydrocarbons and Effect of the π-Congestion on Conformations and Electronic States

Tomohiko Nishiuchi, Seito Aibara, Hiroyasu Sato, Takashi Kubo

2022Journal of the American Chemical Society74 citationsDOIOpen Access PDF

Abstract

produces the twisted triplet.

Topics & Concepts

ChemistrySinglet stateSteric effectsTriplet stateOpen shellComputational chemistrySinglet fissionPhotochemistryChemical physicsStereochemistryMoleculeOrganic chemistryExcited stateAtomic physicsPhysicsSynthesis and Properties of Aromatic CompoundsFullerene Chemistry and ApplicationsAdvanced NMR Techniques and Applications
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