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A 1D Mixed-Valence Cuprofullerene Pyrazolate Polymer as a Semiconductor Material

Jia-Jing Zhong, Shun‐Ze Zhan, Yanzhou Li, You-Shi Guo, Seik Weng Ng, Yi‐Fei Deng, Dan Li

2022Inorganic Chemistry10 citationsDOI

Abstract

[FPz = 4-(trifluoromethyl)pyrazolate], synthesized solvothermally with chlorobenzene as the solvent, is a doubly-connecting trans bis-adduct hexanuclear cuprofullerene that has copper in mixed valence. The compound is an example of a metallofullerene having semiconductivity character.

Topics & Concepts

ChemistryValence (chemistry)ChlorobenzeneTrifluoromethylAdductSolventSemiconductorCopperStereochemistryCrystallographyOrganic chemistryOptoelectronicsCatalysisPhysicsAlkylFullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials ResearchGraphene research and applications