Cyclic(alkyl)(amino)carbene ruthenium complexes for <i>Z</i> -stereoselective (asymmetric) olefin metathesis
Jennifer Morvan, François Vermersch, Jan Lorkowski, Jakub Talcik, Thomas Vivès, Thierry Roisnel, Christophe Crévisy, Nicolas Vanthuyne, Guy Bertrand, Rodolphe Jazzar, Marc Mauduit
Abstract
The first Z -stereoselective catechodithiolate ruthenium complexes containing achiral and chiral cyclic(alkyl)(amino)carbene ligands are reported.
Topics & Concepts
CarbeneRutheniumStereoselectivityAlkylOlefin metathesisChemistryMetathesisOlefin fiberCatalysisStereochemistryMedicinal chemistryOrganic chemistryPolymerizationPolymerSynthetic Organic Chemistry MethodsN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCyclopropane Reaction Mechanisms