Choline chloride–ethylene glycol based deep-eutectic solvents as lixiviants for cobalt recovery from lithium-ion battery cathode materials: are these solvents really green in high-temperature processes?
Nand Peeters, K. Janssens, Dirk De Vos, Koen Binnemans, Sofía Riaño
Abstract
, LCO), which is a common cathode material in lithium-ion batteries. Here, leaching of cobalt is facilitated by reduction of cobalt(iii) to cobalt(ii) in the presence of a reducing agent. However, several recent publications report on the use of DESs as lixiviants at high temperatures (180 °C) without addition of a reducing agent. Typical DESs for these applications are based on mixtures of choline chloride and ethylene glycol (ChCl : EG). Unfortunately, these studies ignore the limited thermal stability of ChCl : EG at high temperatures, which limits the recyclability of this DES. In this work, the drawbacks of using ChCl : EG as the lixiviant in high-temperature ionometallurgical processes are demonstrated. Structural analysis confirmed that ChCl : EG is not stable at 180 °C, forming hazardous and toxic decomposition products such as trimethylamine and 2-chloroethanol. It was hypothesized that choline chloride reduces cobalt(iii) while simultaneously undergoing a radical β-hydrogen abstraction reaction, thereby decomposing to trimethylamine and other degradation products. The main conclusion is that this type of DES should not be used for high-temperature leaching processes due to their limited stability under such conditions.