Room-temperature graphitization in a solid-phase reaction
Sahar Elnobi, Subash Sharma, Mona Ibrahim Araby, Balaram Paudel, Golap Kalita, Mohd Zamri Mohd Yusop, Muhammed Emre Ayhan, Masaki Tanemura
Abstract
/Si substrate for transmission electron microscopy (TEM) and Raman spectroscopy analyses, respectively. The amorphous carbon surroundings and locations between the Ni NPs started to become graphitized during the film deposition even at room temperature (RT) and 50 °C. The graphitization was confirmed by both high-resolution TEM (HR-TEM) and Raman 2D peak analyses. The increase in the relative amount of Ni in the amorphous carbon film led to the partial oxidation of the larger Ni NPs, resulting in less graphitization even at an elevated deposition temperature. Based on the detailed HR-TEM analyses, a decreased oxidation of NPs and enhanced solubility of carbon into Ni NPs were believed to be key for achieving low-temperature graphitization.