Organic photoredox catalyzed dealkylation/acylation of tertiary amines to access amides
Chen Liu, Han-Nan Chen, Tengfei Xiao, Xiu‐Qin Hu, Peng‐Fei Xu, Guo‐Qiang Xu
Abstract
organic photoredox catalysis is presented. In this protocol, a novel organic photocatalyst (Cz-NI-Ph) that showed excellent catalytic performance during C-N bond cleavage is developed. Moreover, this reaction features green and mild conditions, broad substrate scope, and readily available raw materials.
Topics & Concepts
AcylationAlkylationCatalysisChemistryPhotoredox catalysisOrganic chemistryCombinatorial chemistryPhotocatalysisRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesSynthesis and Catalytic Reactions