Electron belt-to-σ-hole switch of noncovalently bound iodine(<scp>i</scp>) atoms in dithiocarbamate metal complexes
Лев Е. Зеленков, Anastasiya A. Eliseeva, Sergey V. Baykov, Vitalii V. Suslonov, Bartomeu Galmés, Antonio Frontera, Vadim Yu. Kukushkin, Daniil M. Ivanov, Nadezhda A. Bokach
Abstract
The nature of metals in the isostructural series of dithiocarbamate complexes affects the electron belt-to-σ-hole switch of noncovalently bound iodine(<sc>i</sc>) leading to either semicoordination, or halogen bonding.
Topics & Concepts
DithiocarbamateIsostructuralHalogenIodineChemistryMetalElectronCrystallographyPhotochemistryOrganic chemistryCrystal structureAlkylQuantum mechanicsPhysicsCrystallography and molecular interactionsOrganometallic Compounds Synthesis and CharacterizationCrystal structures of chemical compounds