Porous Ru(bpy)<sub>3</sub><sup>2+</sup>-Linked Polymers for Recyclable Photocatalysis of Enantioselective Alkylation of Aldehydes
Yi Luo, Ziyue Xu, Hui Wang, Xing‐Wen Sun, Zhan‐Ting Li, Dan‐Wei Zhang
Abstract
cores are prepared via one-pot Suzuki-Miyaura coupling reactions. Both Ru-POPs are thermally stable at up to 340 °C in air and do not dissolve in all solvents tested. One of the POPs has been revealed to be highly effective and reusable as a heterogeneous photocatalyst for visible light-driven enantioselective alkylation of aldehydes. After 10 cycles, the catalyst still maintains the enantioselectivity, while the activity just decreases slightly.
Topics & Concepts
AlkylationEnantioselective synthesisPhotocatalysisCatalysisPolymerMetalMaterials sciencePorosityVisible spectrumOrganic chemistryPolymer chemistryChemistryOptoelectronicsCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications