Stabilization of a high-spin three-coordinate Fe(<scp>iii</scp>) imidyl complex by radical delocalization
Po‐Chun Yang, Kuan-Po Yu, Chi-Tien Hsieh, Junjie Zou, Chia-Te Fang, Hsin‐Kuan Liu, Chih‐Wen Pao, Liang Deng, Mu‐Jeng Cheng, Chun‐Yi Lin
Abstract
A stable three-coordinate Fe imido radical ( i.e. imidyl) complex can be stabilized via N radical delocalization onto the aryl imido substituent.
Topics & Concepts
ChemistryReactivity (psychology)CrystallographyDelocalized electronIntramolecular forceBond lengthLigand (biochemistry)StereochemistryCrystal structureBiochemistryReceptorAlternative medicinePathologyOrganic chemistryMedicineMetal-Catalyzed Oxygenation MechanismsMagnetism in coordination complexesCO2 Reduction Techniques and Catalysts