Aggregation-Induced Luminescence Based UiO-66: Highly Selective Fast-Response Styrene Detection
Fan Yang, Jianzhong Ma, Qian Zhu, Zhonglei Ma, John Wang
Abstract
One of the main pollutants in indoor air is volatile organic compounds (VOCs), which can cause great harm to human health. So the development of a VOC detection technology is of great significance. In this work, a tetraphenylethylene-functionalized UiO-66 based on aggregation-induced emission was successfully prepared. The UiO-66-TBPE structure exhibits the characteristic blue emission of TBPE ligands under UV excitation and can be used as a luminescence sensor for fast and efficient detection of VOCs. More importantly, UiO-66-TBPE has a high fluorescence sensing selectivity in p-xylene and styrene vapor. To further improve the practical performance, we combined UiO-66-TBPE with the polymer polyacrylate (PA) to obtain a flexible hybrid membrane with fast detection performance for styrene vapor within the 30 s. The deeper sensing mechanism of p-xylene and styrene inducing different fluorescence enhancement and fluorescence quenching is explained by a combination of modern characterization techniques and computer simulation. Finally, we applied UiO-66-TBPE/PA to leather and still maintained a good sensing performance. It provides a potential way for the application of fluorescent metal–organic frameworks (MOFs) to detect VOCs in daily life.