Physical properties of porphyrin-based crystalline metal‒organic frameworks
Sreehari Surendran Rajasree, Xinlin Li, Pravas Deria
Abstract
Metal‒organic frameworks (MOFs) are widely studied molecular assemblies that have demonstrated promise for a range of potential applications. Given the unique and well-established photophysical and electrochemical properties of porphyrins, porphyrin-based MOFs are emerging as promising candidates for energy harvesting and conversion applications. Here we discuss the physical properties of porphyrin-based MOFs, highlighting the evolution of various optical and electronic features as a function of their modular framework structures and compositional variations.
Topics & Concepts
PorphyrinMetal-organic frameworkMaterials scienceNanotechnologyModular designElectrochemistryComputer scienceChemistryPhotochemistryOrganic chemistryElectrodePhysical chemistryAdsorptionOperating systemMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesCovalent Organic Framework Applications