Aerial carbon dioxide conversion to carbonate mediated by a lead(<scp>ii</scp>) complex with tridentate bipyridine containing a hydrazide ligand under electrochemical conditions yielding single-component white-light-emitting phosphors
Ghodrat Mahmoudi, Isabel García‐Santos, E. Labisbal, A. Castiñeiras, Vali Alizadeh, Rosa M. Gomila, Antonio Frontera, Damir A. Safin
Abstract
A novel tetranuclear complex [Pb 4 L 4 (CO 3 ) 2 ]·4H 2 O (1·4H 2 O) is reported, which is obtained through electrochemical oxidation of a lead anode under an ambient atmosphere in a CH 3 CN : MeOH solution.
Topics & Concepts
ElectrochemistryChemistryCarbonateLigand (biochemistry)Carbon dioxideAnodeLead dioxideInorganic chemistryPropylene carbonateHydrazideNuclear chemistryPhotochemistryElectrodeOrganic chemistryPhysical chemistryReceptorBiochemistryCO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysisAdvanced Photocatalysis Techniques